{N,N-Bis[2-(diphenylphosphanyl)ethyl]aniline}(η2-dibenzylideneacetone)palladium(0)
نویسندگان
چکیده
In the title complex, [Pd(C(34)H(33)NP(2))(C(17)H(14)O)], the Pd(0) atom is coordinated in a trigonal planar geometry formed by two P atoms of a bis-[(diphenyl-phosphino)eth-yl]aniline ligand and a C=C (η(2)) bond involving the C atoms that are in the α,β positions relative to the central ketone of the dibenzyl-ideneacetone ligand.
منابع مشابه
Crystal structure of unsymmetrical α-diimine palladium(II) complex cis-[{ArN=C(Me)–(Et)C=NAr}PdCl2] [Ar = 2,6-(iPr)2C6H3]
The unsymmetrical α-di-imine ligand N-{2-[2,6-bis-(propan-2-yl)phenylimino]pentan-3-yl-idene}-2,6-bis-(propan-2-yl)aniline, [ArN=C(Me)-(Et)C=NAr] [Ar = 2,6-(iPr)2C6H3], (I), and the corresponding palladium complex, cis-(N-{2-[2,6-bis-(propan-2-yl)phenylimino]pentan-3-yl-idene}-2,6-bis-(propan-2-yl)aniline)di-chlor-ido-palladium(II) 1,2-di-chloro-ethane monosolvate, [PdCl2(C29H42N2)]·C2H4Cl2 or ...
متن کاملBis{N,N-bis[(diphenylphosphanyl)methyl]aniline-κ2 P,P′}copper(I) tetrafluoridoborate
In the cation of the title compound, [Cu(C(32)H(29)NP(2))(2)]BF(4), the Cu(I) atom is four-coordinated in a distorted tetra-hedral geometry by four P atoms from two N,N-bis-[(diphenyl-phosphan-yl)meth-yl]aniline ligands. In the crystal, the cations are linked by C-H⋯π inter-actions, forming chains along the a axis. Intra-molecular C-H⋯N and inter-molecular C-H⋯F hydrogen bonds are also observed.
متن کامل2,6-Bis[1-(2-methylphenylimino)ethyl]pyridine
The mol-ecule of the title compound, C(23)H(23)N(3), which was synthesized by the condensation reaction between 2,6-diacetyl-pyridine and 2-dimethyl-aniline, adopts an E configuration about both C=N imine bonds. The dihedral angles formed by the benzene rings with the pyridine ring are 89.68 (5) and 53.62 (6)°.
متن کامل2,6-Bis[1-(2,6-diethylphenylimino)ethyl]pyridine
The title compound, C(29)H(35)N(3), is the product of the condensation reaction between 2,6-diacetyl-pyridine and 2,6-diethyl-aniline. In the mol-ecule, the pyridyl ring is coplanar with the imino functional groups [torsion angles in the range 177.1 (2)-179.9 (2)°. The two 2,6-diethyl-substituted benzene rings are approximately perpendicular to the ethyl-idenepyridine central core, the dihedral...
متن کاملBis{1-[2-(diphenylphosphanyl)ethyl]-3-ethylimidazol-2-ylidene}nickel(II) diiodide acetonitrile disolvate
The mol-ecular structure of the title compound, [Ni(C(19)H(21)N(2)P)(2)]I(2)·2CH(3)CN, shows two six-membered N-heterocyclic carbene/phosphane chelate rings that form a nearly square-planar coordination geometry around the Ni(II) atom, which lies 0.190 (1) Å above the C(2)P(2) plane. The sum of the bond angles at the Ni(II) atom is 358.68 (6)°, with C-Ni-P bite angles of 82.89 (5) and 84.08 (6)...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011